The local foam installer that I used here in Hilton Head told me he looked for some peeling back of the foam. This was ensuring that it was at the perfect temperature which helped them maximize their yield (profit). I have open cell foam and it pulled away a little, and did so immediately (within minutes). They went back after they were done to any spots that pulled away too much and filled them with the touch up kit; they were looking for the top edge to roll just a little bit. 
We have a 1950's ranch in Atlanta and are interviewing foam contractors to spray open cell under the roof, with an "ankle wall" out towards the eaves to seal the attic. My wife and daughters are chemically sensitive, so I'm trying to figure out how to minimize the fumes coming into the house. Additionally, at least one contractor has offered (for > $900) to remove our existing rock wool & R-13 fibreglass from the attic floor to "increase cross-ventilation into the attic". Seems to me I can't both minimize fumes AND increase cross-ventilation. They also offered to spray a fire-retardant on for >$600. Would ventilation during installation help any or woud the retardant seal off the foam and help that way? Thanks...
One of the key differentiators between traditional insulation materials and spray foam insulation is the latter’s ability to insulate and air seal. Foam insulation provides an air barrier to wherever it is applied to help mitigate air leakage from the building. Air sealing the building envelope with sprayed-in foam insulation also helps address moisture ingress to reduce the risk of mold and mildew growth as well as the formation of ice dams in colder climate zones during the winter months.  When you compare foam insulation with traditional fiberglass insulation and cellulose insulation, sprayed insulation minimizes air infiltration, it assists in limiting moisture vapor from entering and escaping the home, which in turn reduces the load on heating and cooling systems. Below is a video that compares fiberglass, cellulose and open-cell spray foam in terms of insulating and air sealing value.
I used this for the rim-joist in our home. A couple things: I put 1in solid core foam (cut to size) in each bay before using the spray foam. I also was able to do a relatively 'thick' spray to close off any potential gaps that may have existed. I turned off the HVAC and turned on some fans in the windows to exhaust out the fumes, and wore a mask (3m respirator).
You probably have some familiarity with spray foam insulation, and you may have even used the foam that comes in pressured spray cans at home improvement retailers. This foam is know as one-part foam, meaning that it is one continuous mixture that is simply applied to the area in need. One-part foam is frequently used for sealing small gaps and cracks.

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c) Make sure that the over expanded access is properly removed from the walls. We had a junior cutter taking too much off by bending his saw into the cavity. Look closely at the inside wall corners, and ceiling/wall corners to make sure that the foam is properly removed flush with the studs. If it has not been cut back flush it may lead to uneven drywall finishes .
I'm in the process of redoing my basement and read through the posts. I took out one inch styrofoam covered by 1/4 " beadboard and installed 2X4s and plan on putting in fiberglass batts between them(r-13) with 1/2 in drywall over top of that. Do you think I will see a significat increase in heat control? Should I have done more?... it's a little after the fact, but still curious to know if I will see a big difference based on your experience.

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