If you don't have the patience to slowly fill the void with spray foam through holes drilled in one of the studs, you could (if you were an experienced carpenter) use a Sawzall to remove one of the studs and re-frame the corner as a two-stud corner. Then you could either insulate the void with a fiberglass batt or simply present the two-stud corner to the spray-foam contractor as an accessible corner.
If you're chemically sensitive, it's probably not a good idea to get it installed, but it's also not a good idea to breathe musty air from the crawl space either. In addition, your house and its contents are made of lots of materials that affect your indoor air quality. If you're really concerned about this, hire a company to test your air and tell you what you can do about it.

Spray foam insulation, when properly installed is both an air barrier and when closed cell foam is used at the proper depth a vapor barrier!  Before hiring any contractor you should establish the brand of foam being used and verify that with the named manufacture.  Please ask for ESR reports and MSDS sheets on any foam being installed in your home. A couple areas where you might consider spray foam insulation include: http://www.youtube.com/v/ggLAUsiuI_o&feature=share

During colder months, 2 component foam is very sensitive to temperature variances. Per product instructions, both tank temperatures need to be above 70°F (21°C) for at least 24 hours prior to use. All application surfaces should be clean/dry and above 60°F (16°C) prior to application. Variance outside of the recommended temperature can affect foam yield and performance.
Medium-density foam is applied as low or high-pressure two-component polyurethane spray foam. Medium-density foam offers specific benefits depending on the climate and the type of building in which it is used. Like low-density foam, medium-density SPF is often used for continuous insulation, interior wall cavity fill, and unvented attic applications. However, medium-density is a closed-cell spray foam; it is often used where there is need for the greatest R-value insulation per inch possible. Medium-density foam acts as an air, vapor, and water barrier, and can even help reduce noise.
Fill and seal expanding foam sealant is urethane Fill and seal expanding foam sealant is urethane foam designed to fill large areas quickly and permanently. Uses include filling holes cracks or gaps that require a complete airtight and waterproof seal but are too large to be filled with ordinary caulk. The foam expands approximately 3 times its original ...  More + Product Details Close

Roof Coating Seal

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