Thoroughly clean the roof surface. Roofs collect oils from asphalt, chimneys, and cars plus lots of dirt and dust. Coatings don’t stick well to any of these. We recommend cleaning with an inexpensive solution of TSP or TSP Substitute in a bucket of water (follow label instructions). Use a broom to scrub ponding areas and areas of peeling coatings. Work a section at a time and hose off the dirty water. Sweep away puddles to promote drying. Do not allow wash water to dry on walls, furniture, windows, and visible surfaces. 
Today’s “third generation” of blowing agents have a GWP of 700 to 1000 which is still remarkably high considering water/CO2 has a GWP of 1. However, innovation from some chemical manufacturers like the Chemours Company have introduced the next generation of HFO blowing agents such as Opteon 1100, which significantly reduces the GWP impact when using closed-cell spray foam insulation products.

Most flat roofs are not perfectly sloped, causing water to puddle in some areas, in particular around the drains and scuppers. Many roof coatings are not rated or warranted for "ponding water", and thus might fail pre-maturely if exposed to standing water over long periods of time. Serious consideration should be given to the performance and limitations of the coating being selected. Some manufacturers will warranty their coatings including ponding water. Typically, manufacturers for acrylic roof coatings do not include warranties for ponding water, while some polyurethane and silicone roof coatings manufacturers will.

This is in great contrast to my friend's experience. Her attic spaces were sprayed and the foam is actually pretty, and I was in her attic 6-7 days after it was sprayed and could hardly smell anything when I stuck my face up to the foam. And she did not have to clean up one speck of dust during or after the spraying. I got the name/number of the guy from her who managed her attic project, but between the time he did my house and the time he did her house, he was let go from the company who did her attic and hired by another company. He assured me everything would be the same, etc., etc., and I had no reason to believe anything had changed, but the sprayers who did my house later admitted they had never sprayed an attic before and I also found out that the foam used in my attic was from a different manufacturer. Neither my friend nor I had any idea this guy was with different company then, until the week after they filled my attic with off ratio foam, and my home with toxic vapors.  
Spray polyurethan foam does effectly prevent all six of these heat transfer methods from occurring. These should be the mechanisms by which you judge insulation, in addition to their R-Value. If you're uncertain about installing spray foam insulation, Energy Star has a map that recommends levels of insulation by R-value and cost-effectiveness in the United States.
I'm in the process of redoing my basement and read through the posts. I took out one inch styrofoam covered by 1/4 " beadboard and installed 2X4s and plan on putting in fiberglass batts between them(r-13) with 1/2 in drywall over top of that. Do you think I will see a significat increase in heat control? Should I have done more?... it's a little after the fact, but still curious to know if I will see a big difference based on your experience.

Roof Coating Colorado

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