Roof coatings can add 25 years to the service life of a roof and reduce the amount of discarded roofing materials that end up in landfills. The infrared image on the right shows 175 °F (79 °C) on the uncoated (black) section of the modified bitumen roof. The coated (white) section is 79 °F (26 °C). Field studies have shown that cool roof coatings can lower rooftop temperatures and reduce air conditioning bills.
If you're chemically sensitive, it's probably not a good idea to get it installed, but it's also not a good idea to breathe musty air from the crawl space either. In addition, your house and its contents are made of lots of materials that affect your indoor air quality. If you're really concerned about this, hire a company to test your air and tell you what you can do about it.
Spray polyurethan foam does effectly prevent all six of these heat transfer methods from occurring. These should be the mechanisms by which you judge insulation, in addition to their R-Value. If you're uncertain about installing spray foam insulation, Energy Star has a map that recommends levels of insulation by R-value and cost-effectiveness in the United States.
If your foam pulled away just a little bit, Jamie, and they were able to fix it with just a little bit of touching up, then it wasn't as bad as the house where I saw this problem. As the last photo above shows, it had pulled away significantly from the studs and rafters, and it was all over the house. This was closed cell foam, and interestingly, it didn't pull away from the horizontal framing members, just the vertical and sloped ones. They did some touch up, but that wasn't enough. I don't know how this one ended up getting resolved. I think maybe the contractor came back and sprayed cellulose on top of the foam.
Both high and low-pressure, two-component spray foam are applied by professional contractors who are trained to use and apply SPF with the required equipment (protective gear, full eye protection, respirators, and gloves). Contractors should follow the ventilation recommendations by the product manufacturer to avoid overexposure through inhalation, and instruct those without protective gear (homeowners or building occupants) to stay away from the work area during exposure times and to not return until instructed by the professional contractor.
High-pressure systems can be used to spray all three types of spray polyurethane foam. Of the three types of spray foam used in building insulation and weatherization, the high-pressure, two-component spray foam is most likely to be used on larger projects such as a new building construction or renovations. SPF applied with a high-pressure system tends to adhere tightly to the entire structure which helps avoid sagging or detaching from its position. It can also provide a seal against air and insects.
I'm in the process of redoing my basement and read through the posts. I took out one inch styrofoam covered by 1/4 " beadboard and installed 2X4s and plan on putting in fiberglass batts between them(r-13) with 1/2 in drywall over top of that. Do you think I will see a significat increase in heat control? Should I have done more?... it's a little after the fact, but still curious to know if I will see a big difference based on your experience.
Jennifer, I'm not an expert on the health effects of closed cell foam. A lot of people live in houses with closed cell foam and have no health problems from it, at least not short-term, acute problems. I do know of one person who had it removed from her crawl space because she was convinced it caused her dog to get sick, but I know only what she told me.  
Part of that guidance will be explaining that interior, two component foam is applied with the professional using specific personal protective equipment (high-pressure foam is installed while using a respirator, for example). It is encouraged that professionals explain clearly to customers that this equipment, coupled with certain work and engineering practices, including ventilation, is used to minimize exposures to the chemicals used to make SPF during the job.
Air infiltration and exfiltration within a home contributes to almost 99% of moisture migration. Restricting air movement stops moisture accumulation so that the possibility of mold growth is less likely. Combined with a properly sized HVAC system, spray foam insulation helps control the indoor humidity levels to minimize moisture and condensation. Reducing moisture and controlling humidity can also add years to the life expectancy of a home, plus contribute to a healthier indoor environment. Finally, it also deters pests, making it difficult for them to nest.
Note:  A board foot is defined as a 12" x 12" square at 1" thick. Actual output can be affected by a number of factors including temperature and humidity. The theoretical yield has become an industry standard for identifying certain sizes of two component kits. Theoretical yield calculations are performed in perfect laboratory conditions, without taking into account the loss of blowing agent or the variations in application methods and types.
Due to its relatively large cell structure, low-density foam stays somewhat soft and flexible after curing. This increases the likelihood of its continuing to provide high insulation value even as the building settles and shifts over time. Low-density SPF provides heat insulation and seals airflow through cracks, joints and seams by filling the cavities. In addition, this foam can help absorb sound thanks to its soft texture and open-cell structure.
SPF insulation applied by professionals is usually described as either a high- or low-pressure foam and is available as either open- or closed-cell. Each type has advantages and disadvantages depending on the application requirements. The comparison chart below can be helpful in explaining or understanding which type of SPF insulation is best suited to a specific application.

How Much Is A Board Foot Of Spray Foam

Starting a new build (1 1/2 basement walkout), all 2x6 exterior walls w/ brick veneer in CZ3. Above grade, would like to do spray foam in 2x6 walls, 1/2" or 1" of rigid foam board on the exterior, and a 1" air gap. Will this require a house wrap or can I do w/o the rigid foam and go with a housewrap? Also, any recommendations about insulation strategies for the finished basement. Thanks!

If you cut the nails holding one of the corner studs to the bottom plate and the top plate with a Sawzall, you can use a flat bar (or a flat bar plus a wrecking bar) to pull the stud off the sheathing nails. Either re-use the stud, or buy a new stud, and install the stud with toenails as shown in the link I provided in Comment #51 (this link: Outside corner detail).

How Much Will Spray Foam Save Me