Jennifer, I'm not an expert on the health effects of closed cell foam. A lot of people live in houses with closed cell foam and have no health problems from it, at least not short-term, acute problems. I do know of one person who had it removed from her crawl space because she was convinced it caused her dog to get sick, but I know only what she told me.  
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Spray foam insulation, when properly installed is both an air barrier and when closed cell foam is used at the proper depth a vapor barrier!  Before hiring any contractor you should establish the brand of foam being used and verify that with the named manufacture.  Please ask for ESR reports and MSDS sheets on any foam being installed in your home. A couple areas where you might consider spray foam insulation include: http://www.youtube.com/v/ggLAUsiuI_o&feature=share
We had issues with getting this foam to turn green in summertime in the South. We needed up spending an additional $300 on being able to spray this foam: 110 window a/c for shop & a $60 tarp to drape over the top, to keep the temps down. The areas where we had trouble-shooted were sticky & even after we wiped it down, the new green foam wouldn't stick. My husband had to apply Liquid Nails to it. For over $800, I expected alot more, plus the sellers customer service skills were in need of improvement.
Installations present a number of considerations and recommendations in order to provide a safe environment for application and to avoid overexposure through inhalation. Appropriate ventilation and protective gear is required when applying insulating foam sealant. Installers should wear protective gear, often referred to as “personal protective equipment” (PPE), such as protective clothing, gloves, and eye protection. Direct skin contact should be avoided, and recommendations by the product manufacturer should be followed.
The average price to cover 200 square feet with a foam insulation kit will run between $300 and $600 (about two to three kits). Inside these kits is something called Icynene, a foam made from two liquids that are heated and pushed through a gun on the can. When Icynene is released, it expands up to 100 times its size as it hits the surface area you're covering. These can contain a lot of gasses, making its installation a dangerous process. Even low-pressure sprayers can be harmful to homeowners' health.
In the case you have above the installer wasn't reading his foam. They must be trained to do that as they spray. Temps and conditions are constantly changing thru out the day. Either he wasn't properly trained or if he was,he wasn't doing his job! This is a serious problem with people jumping in to the foam business. A lot of homeowners and builders are looking the best price and end up with someone who doesn't know what they are doing. Hope this info helps. Foam insulation is a great product. It just has to be done right by someone who knows what they are doing.
Heat which is created elsewhere that is transported by means of a fluid, such as water or in our case air. Spray foam insulation's most important attribute is the ability to air seal creating a custom airtight envelope within the building structure. The added benefit to air sealing is the ability to block convective heat transfer from interior to exterior during heating months and vice versa during cooling months, as the heat cannot escape through gaps in the buildings envelope without the aid of air movement from infiltration as a means of transport.

Light-density open-cell SPF is commonly known as half-pound foam. It is a semi-rigid material with a sponge-like appearance that expands during installation and creates small, open cells that are filled with carbon dioxide. Due to its ability to expand during the application process, it fills cracks, crevices and voids and adheres to irregular surfaces or substrates to form an air sealing insulation.[12] https://www.youtube.com/watch?v=ggLAUsiuI_o&feature=kp


Steve: If your spray foam installer leaves the vents open, he will be committing the 2nd of the 4 problems I described above. You will most likely have comfort and efficiency problems. You may well have condensation problems. You will be spending a lot of money on a product that likely won't perform as it should. Don't let him leave the vents open. If the installer you've chosen doesn't understand this, you may want to choose someone else. 

In the early days of insulating attics, people believed the insulation was a heat source. That’s not the case, as the insulation is actually a barrier between two areas of different temperatures. As for the “hot roof” theory, the unvented attic system could make the temperature of the roof go up a little, but this increase won’t cause damage to your shingles. https://youtube.com/v/ggLAUsiuI_o?version=3
One of the key differentiators between traditional insulation materials and spray foam insulation is the latter’s ability to insulate and air seal. Foam insulation provides an air barrier to wherever it is applied to help mitigate air leakage from the building. Air sealing the building envelope with sprayed-in foam insulation also helps address moisture ingress to reduce the risk of mold and mildew growth as well as the formation of ice dams in colder climate zones during the winter months.  When you compare foam insulation with traditional fiberglass insulation and cellulose insulation, sprayed insulation minimizes air infiltration, it assists in limiting moisture vapor from entering and escaping the home, which in turn reduces the load on heating and cooling systems. Below is a video that compares fiberglass, cellulose and open-cell spray foam in terms of insulating and air sealing value. 

How Much To Spray Foam Basement

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