If you don't have the patience to slowly fill the void with spray foam through holes drilled in one of the studs, you could (if you were an experienced carpenter) use a Sawzall to remove one of the studs and re-frame the corner as a two-stud corner. Then you could either insulate the void with a fiberglass batt or simply present the two-stud corner to the spray-foam contractor as an accessible corner.
I have never used foam insulation before and this was easy for me to use right out of the box. I had a 4'x8"x8" cavity in my basement that houses a waterline. When the previous homeowner installed this they put no insulation in at all and being that it's an exterior wall in the basement and I live in the Midwest that thing was pushing so much cold air in it was incredibly uncomfortable. Out of the box and job completed in about 5 minutes. Stopped all drafts and created a nice 2" barrier on the wall in which I will install some extra bat insulation over it. 4 stars because the spray isn't very good passed 6-8" from the surface. Make sure you can reach the surface you want to coat. Great for small jobs! http://youtube.com/watch?v=ggLAUsiuI_o&app=desktop
Part of that guidance will be explaining that interior, two component foam is applied with the professional using specific personal protective equipment (high-pressure foam is installed while using a respirator, for example). It is encouraged that professionals explain clearly to customers that this equipment, coupled with certain work and engineering practices, including ventilation, is used to minimize exposures to the chemicals used to make SPF during the job.

Spray Foam Contractors


Builders often turn to high-density SPF when high insulation values and strength are needed. As its name implies, this foam has a denser structure than either of the other SPF types. Therefore, it does not expand as much as lower density foams and requires more material to cover and insulate any given space. This spray foam is often an excellent choice for roofing or other exterior insulation because of its seamless, monolithic nature. High-density SPF can also help reduce energy costs significantly over a roof’s lifetime due to its thermal resistance properties. It also offers increased protection against air and water infiltration and strengthens the structure to which it is applied. The bond that SPF forms to the roof can increase a building’s resistance to wind uplift, which can help reduce damage experienced during periods of high wind.
Today’s “third generation” of blowing agents have a GWP of 700 to 1000 which is still remarkably high considering water/CO2 has a GWP of 1. However, innovation from some chemical manufacturers like the Chemours Company have introduced the next generation of HFO blowing agents such as Opteon 1100, which significantly reduces the GWP impact when using closed-cell spray foam insulation products.
Before you decide on spray foam or another method of insulation, it's important to understand the superiority of spray foam compared to traditional materials. When compared to fiberglass batts, spray foam offers nearly double the R-value per inch, achieves air-sealing and insulation in one step, won't be damaged by mold or moisture, and won't settle, compress, or otherwise be damaged to the point it needs replacement.
When it comes to insulating the house, fiberglass tends to be the common form of insulation. However, after comparing fiberglass and spray foam insulation, it’s shocking how fiberglass tends to be the lesser of the two. Although it has deemed reliable over the years, there are way more benefits to insulating your home with spray foam. One of those benefits includes regulating the temperature of your house.
Carefully examine the roof membrane (surface material) for cracks, tears, blisters, evidence of ponding, exposed foam, and open seams. If already coated, evaluate the condition of the coating. Pay particular attention to areas around roof penetrations (vents, skylights, pipes, etc), ponding areas, cracks in parapet walls, and the attachment of roof membranes to parapet walls. Roofs should be in good condition to warrant coating.
RE: my June 12 post...We went ahead and had the attic sprayed with a Soy-based product. Stayed in a hotel for 3 nites. Still smelled a little bad but that's gone away over time. I'm very glad we didn't use the other foam as even that much outgassing of a petrochemical could have sent my wife to the hospital. Unfortunately, the spray crew didn't speak English(at least not to me) and were kinda lazy, so they ended up spraying over some can fixtures from the kitchen below that were not insulation-contact rated. So I hired an electrician to come out, pull down the cans, pull out what he thought was an appropriate amount of foam to create a big enough air space and then re-install the cans. I billed the firm for the electrician plus an extra night we had to stay in the hotel and they paid, no questions asked. Guess they knew they had screwed up.  
Builders often turn to high-density SPF when high insulation values and strength are needed. As its name implies, this foam has a denser structure than either of the other SPF types. Therefore, it does not expand as much as lower density foams and requires more material to cover and insulate any given space. This spray foam is often an excellent choice for roofing or other exterior insulation because of its seamless, monolithic nature. High-density SPF can also help reduce energy costs significantly over a roof’s lifetime due to its thermal resistance properties. It also offers increased protection against air and water infiltration and strengthens the structure to which it is applied. The bond that SPF forms to the roof can increase a building’s resistance to wind uplift, which can help reduce damage experienced during periods of high wind. http://www.youtube.com/watch?v=ggLAUsiuI_o&feature=kp
Closed-cell (aka two-pound foam) is denser than open-cell at about 2 pounds per cubic foot. Its R-Value is between 6-6.5 per inch. As a result, this kind of foam is much more expensive than its counterpart. The reason closed-cell doesn't need a vapor retarder is because it already has one. It's permeance is 0.8 perm, which means it can handle cold climates without the use of an additional board or drywall. Closed-cell uses hydroflurocarbons (HFCs) as part of its makeup. However, this material has been known to have a high global warming effect. If you want a green insulation solution, this is not the material to use. A way to avoid this and still use closed-cell is by installing it alongside fiberglass batts.

R-value is the term given to thermal resistance to heat flow. The higher the R-value of an insulation product, the more effective the insulation properties. Spray polyurethane foam comes in a range of densities and cel structure. Low density foams are referred to as Open Cel SPF while higher density foams are referred to as Closed Cel foam. 1.8-2 pound polyurethane foam has the highest R-value of readily available spray foam insulation used in homes and buildings.[4]

Roof Spray Foam Insulation

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