The process by which heat energy in the form of light (usually IR unless the substrate is hot enough to glow in the visible range) is emitted more strongly by warm surfaces and absorbed by other materials especially those of low IR reflectivity (think matte black finish). Radiant heat transfer does not require a medium. Foam insulation materials, such as spray foam insulation, are opaque to thermal radiation, like most solid materials.
For large jobs, professionals such as Dr. Energy Saver use two-part foam, which comes in larger containers. With 2-part spray foam, it's necessary to mix separate resin and catalyst compounds at the application nozzle. Combining these ingredients starts a chemical reaction that creates expanding foam. Contractors use small 2-part foam "kits" to air-seal an attic or to seal and insulate ductwork. To insulate an entire attic or wood-framed wall with spray foam, the resin and catalyst compounds are pumped to the application nozzle from 50-gallon drums in a specially equipped truck.