This is more common with closed cell foam, but it happens with open cell foam, too. Since closed cell foam has a higher R-value per inch, installers generally spray 2" in walls and 3" in rooflines to meet the energy code requirements of R-13 and R-19, respectively. (I'm not going to dive into the energy code here, but these numbers apply to many climate zones, the latter being allowed under the UA tradeoffs rule. See the Energy Nerd's blog on this topic if you want to argue.)
I was hesitant to buy this because many reviews stated that it didn't cover as advertised, but after reading/following all directions, everything turned out perfectly. It even seemed to apply slightly more than the 650 bd/ft that was advertised. The application process was very easy to learn and I applied all of the product in about 1 hour and 10 minutes- prep time included. I couldn't be happier and I purchased another kit this morning.

How Much Is Spray Foam Insulation Per Sq Ft

If you don't have the patience to slowly fill the void with spray foam through holes drilled in one of the studs, you could (if you were an experienced carpenter) use a Sawzall to remove one of the studs and re-frame the corner as a two-stud corner. Then you could either insulate the void with a fiberglass batt or simply present the two-stud corner to the spray-foam contractor as an accessible corner.
R-value is the term given to thermal resistance to heat flow. The higher the R-value of an insulation product, the more effective the insulation properties. Spray polyurethane foam comes in a range of densities and cel structure. Low density foams are referred to as Open Cel SPF while higher density foams are referred to as Closed Cel foam. 1.8-2 pound polyurethane foam has the highest R-value of readily available spray foam insulation used in homes and buildings.[4]

Roof Spray Foam Insulation