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I don't even want to ask this question but... several years ago we hired a local contractor to spray high density foam on the roof deck and walls of our unfinished 2nd floor. We realized that the job was done poorly and cut an access into the attic space to assess things. We realize now that they spray foamed directly to the chimney (no flashing). The chimney is currently used for a woodstove and DHW venting. The DHW will go away but wood stove will remain. My question is, how bad (unsafe) is this? I have found information on foam exposure to fire but have not been able to find anything about temperature ratings in general (i.e. what happens on prolonged exposure to high temperatures).
During colder months, 2 component foam is very sensitive to temperature variances. Per product instructions, both tank temperatures need to be above 70°F (21°C) for at least 24 hours prior to use. All application surfaces should be clean/dry and above 60°F (16°C) prior to application. Variance outside of the recommended temperature can affect foam yield and performance.
Silicone coatings are typically produced by adding a catalyst and solvents to a silicone base. Because the silicone is a natural material, these coatings are bio-degradable. They can be applied to a roofing system using many different techniques, including spraying or rolling. Silicone coatings are available in many colors, including reflective white and translucent.

Even for these unique circumstances, InsulBloc is an excellent barrier to dust, drafts, pollen, and noise pollution. This sustainable product is once installed seals any construction gaps or tiny cracks to block heat flow bypass of the insulation membrane. All of this means InsulBloc® outperforms every other insulation system on the market, providing superior operational energy and cost savings.
If your foam pulled away just a little bit, Jamie, and they were able to fix it with just a little bit of touching up, then it wasn't as bad as the house where I saw this problem. As the last photo above shows, it had pulled away significantly from the studs and rafters, and it was all over the house. This was closed cell foam, and interestingly, it didn't pull away from the horizontal framing members, just the vertical and sloped ones. They did some touch up, but that wasn't enough. I don't know how this one ended up getting resolved. I think maybe the contractor came back and sprayed cellulose on top of the foam.

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